Q.In a hydrogen atom, the electron revolving in the fourth orbit has angular momentum equal to
Concept understanding — Bohr Model Quantization
Why does an electron not spiral into the nucleus?
Imagine you're pushing a child on a swing. If you push at random moments, the swing jerks and slows down. But if you push exactly in rhythm with the swing's natural motion, each push adds energy smoothly and the swing goes higher and higher. The swing "prefers" to move at specific frequencies — its natural modes.
An electron orbiting a nucleus is similar, but with a crucial twist from the quantum world. Classical physics says an accelerating charge (like an electron going in a circle) must continuously radiate energy. If that were true, the electron would lose energy, spiral into the nucleus, and atoms would collapse in a flash of light. But atoms are stable. So something is fundamentally different.
The radical idea: allowed orbits only
Niels Bohr proposed in 1913 that the electron cannot occupy just any orbit. It can only exist in certain stationary states — orbits where it does not radiate energy. These are like the swing's natural frequencies, but for an electron.
The key condition that picks out these special orbits is called quantization of angular momentum.
L=n2πh,n=1,2,3,…
Here L is the orbital angular momentum of the electron, h is Planck's constant, and n is a positive integer called the principal quantum number.
What this means physically
Angular momentum for a circular orbit is L=mvr, where m is the electron mass, v its speed, and r the orbit radius. So the quantization condition becomes:
mvr=n2πh
This is not a formula you derive — it is a postulate, a rule that nature follows. Bohr had no deeper explanation for why this rule works; he simply noticed it gave the right answers for hydrogen's spectrum.
The quantity 2πh appears so often that it has its own symbol: ℏ (h-bar). So the condition is often written as L=nℏ.
What it predicts
Combining this quantization with Newton's law for circular motion (centripetal force = Coulomb attraction) gives:
- Radius of the nth orbit: rn=n2a0, where a0=0.529A˚ is the Bohr radius (the smallest orbit, n=1).
- Energy of the nth orbit: En=−n213.6eV
The negative sign means the electron is bound to the nucleus. As n increases, the orbit gets larger and the energy becomes less negative (closer to zero).
The key insight for exams
Bohr quantization is not a derivation — it is a condition you apply. When you see a problem about hydrogen-like atoms (one electron), you:
- Write mvr=nℏ
- Write the force balance: rmv2=r2kZe2 (for nuclear charge Ze)
- Solve for r and v in terms of n
Bohr's model works perfectly only for single-electron systems: H, He+, Li2+, etc. It fails for multi-electron atoms because it ignores electron-electron repulsion and the wave nature of electrons.
Why "quantization"?
The word comes from the Latin quantus — "how much." In classical physics, angular momentum can take any value. In Bohr's atom, it comes only in discrete packets (quanta) of size ℏ. This is the first hint that at the atomic scale, nature is not continuous but granular.
The electron does not spiral because it cannot lose energy gradually — it can only jump from one allowed orbit to another, emitting or absorbing a photon of exactly the right energy. Between these jumps, it simply exists in a stationary state, defying classical expectations.
Bohr's quantization of angular momentum is one of the defining postulates covered in the NCERT Class 12 Physics Atoms chapter, and students frequently search for "Bohr model quantization condition and derivation" or "Bohr's model important questions" while preparing for CBSE boards and JEE Main/NEET. This concept is also a common launching point for numerical problems on orbital radius and energy levels of hydrogen-like atoms tested across competitive exams.
Why this formula?
Why Angular Momentum is Quantised in the Bohr Model
The Bohr model's most famous result — that angular momentum comes only in integer multiples of 2πh — is not an arbitrary assumption. It follows directly from a single, elegant idea: the electron's wave must close on itself.
The core problem Bohr faced
By 1913, physicists knew two things that seemed contradictory:
- Rutherford's nuclear model showed electrons orbiting the nucleus.
- Maxwell's equations predicted that any accelerating charge (like an orbiting electron) must radiate energy, spiral inward, and collapse in about 10−11 seconds.
Atoms are stable. Something was missing.
Bohr's breakthrough was to combine the newly discovered quantum idea (Planck's constant h) with classical mechanics, but only for allowed orbits. The key constraint came from thinking of the electron not as a tiny planet, but as a standing wave.
The de Broglie wavelength argument (the cleanest derivation)
A few years after Bohr, de Broglie proposed that every moving particle has a wavelength:
λ=ph=mvh
For an electron in a circular orbit of radius r, the circumference is 2πr. For the wave to be stable — not cancelling itself out — the circumference must contain an integer number of wavelengths:
2πr=nλ,n=1,2,3,…
Substitute λ=h/(mv):
2πr=n⋅mvh
Rearrange:
mvr=n⋅2πh
That's it. The left side mvr is the angular momentum L. So:
L=nℏ,where ℏ=2πh
This is not a separate postulate — it is a consequence of requiring the electron wave to be a standing wave. If the wave doesn't close on itself, it interferes destructively and the orbit cannot exist.
Why this fixes the energy levels
Once angular momentum is quantised, the rest follows from classical physics. For a circular orbit, the centripetal force is provided by the Coulomb attraction:
rmv2=4πϵ01r2e2
Combine this with mvr=nℏ and solve for r and E:
rn=me24πϵ0ℏ2⋅n2=a0n2
En=−8ϵ02h2me4⋅n21=−n213.6 eV
A common mistake is to think Bohr derived the quantization rule from first principles. He didn't — he postulated it. The de Broglie standing-wave argument came later and provides the physical reason for the postulate, but it is still a postulate in the full quantum theory.
The deeper reason: it's not really about orbits
The Bohr model is ultimately wrong — electrons don't orbit in neat circles. But the quantization of angular momentum survives in the full quantum mechanical treatment (Schrödinger equation) as the condition that the wavefunction must be single-valued. For the hydrogen atom, the angular momentum quantum number l can take values 0,1,2,…,n−1, and the magnitude is l(l+1)ℏ, not nℏ.
Yet the Bohr model's key insight — that only certain discrete states are allowed — remains the foundation of atomic physics. The formula L=nℏ is the simplest example of a quantum number, and it correctly predicts the hydrogen spectrum to within fine-structure corrections.
The Bohr quantization condition L=nℏ is a boundary condition on the electron wave, not a dynamical law. It says: for the electron to exist in a stable state, its wave must fit perfectly around the nucleus. This is the same principle that governs standing waves on a string or in an organ pipe — only certain wavelengths survive.
Angular momentum in the Bohr model is quantised as l=nℏ=nh/2π.
(d) π2h
Step 1. Bohr's quantisation condition states the angular momentum of an electron in the nth orbit is l=n2πh.
Step 2. For the fourth orbit, n=4:
l=4×2πh=2π4h=π2h
Step 3. This matches option (d). Option (a) would be n=2π (not an integer orbit label), option (b) is the n=1 (ground state) value, and option (c) 4h/π is twice too large (a common slip is forgetting the factor of 2 in 2π in the denominator).
(d) π2h
- Dropping the factor of 2 from 2π in the denominator, which doubles the answer incorrectly.
- Confusing the orbit number n=4 with the angular momentum value itself.
Showing the 12 most recent of 29 on this concept.
- CBSE 2026Set 55/2/11 markMCQQ.In Bohr model of hydrogen atom, for large values of n, the distance between the consecutive orbits is proportional to (A) n (B) n (C) n2 (D) n3
›Reveal solutionSolution
In the Bohr model, the orbital radius scales as rn∝n2. For large n, the gap between consecutive orbits Δr=rn+1−rn behaves like 2n+1, which is proportional to n — so the answer is (B).
The Bohr model gives a beautifully simple picture of the hydrogen atom: electrons orbit the nucleus in fixed circular paths, with quantised angular momentum. The radius of the n-th orbit is
rn=πme2n2h2ε0or, more compactly,rn=a0n2,
where a0≈0.529A˚ is the Bohr radius. So the radius grows as n2.
The question asks about the distance between consecutive orbits — that is, the difference rn+1−rn — for large n. Many students instinctively think this difference is constant, or that it grows like n2 because the radii themselves do. But a difference between two quadratic terms behaves differently from either term alone. Let’s work it out.
- Write the radii for two neighbouring orbits:
rn=a0n2,rn+1=a0(n+1)2.
- The gap between them is
Δr=rn+1−rn=a0[(n+1)2−n2].
- Expand (n+1)2=n2+2n+1. Then
Δr=a0(n2+2n+1−n2)=a0(2n+1).
- For large n, the constant 1 becomes negligible compared to 2n. So
Δr≈2a0n.
Thus the spacing between consecutive orbits is proportional to n itself — not n2, not n, not n3.
Watch outA common mistake is to think that because rn∝n2, the difference must also be ∝n2. But the difference of two squares is linear in n: (n+1)2−n2=2n+1. Always check the actual difference, not just the scaling of the individual term.
TipThis is a neat example of how a discrete difference approximates a derivative: dndr∝2n, which is linear in n. For large n, the Bohr atom’s orbits get farther apart linearly — a fact that connects to the correspondence principle, where classical behaviour emerges.
✓Final answerThe distance between consecutive orbits is proportional to n, so the correct option is (B).
- CBSE 2026Set A1 markMCQQ.The radius of the lowest Bohr's orbit in hydrogen atom is r0. The radius of Bohr's second orbit is (A) r0 (B) 2r0 (C) 4r0 (D) r0/2
›Reveal solutionSolution
Bohr radii scale as n², so r₂ = 4 r₀.
In Bohr's model of hydrogen the radius of the n-th orbit is:
rn=n2r0
where r0 is the radius of the lowest (ground-state, n=1) orbit. For the second orbit, n=2:
r2=22r0=4r0.
✓Final answer(C) 4r₀.
- CBSE 2026Set ANNUAL1 markMCQQ.If the first Bohr radius of hydrogen atom be R, then the radius of the third orbit is(a) 9R(b) R/3(c) 3R(d) R/9
›Reveal solutionSolution
Bohr radius of the nth orbit scales as n2, so the third orbit's radius is 9R.
In the Bohr model, the radius of the nth orbit of the hydrogen atom is
rn=n2r1
where r1 is the radius of the first orbit (given as R here). For n=3:
r3=32×R=9R
✓Final answer(a) 9R.
- CBSE 2026Set ANNUAL1 markMCQQ.Case study: Bohr's model addressed the instability of the Rutherford model by introducing quantization. The model is based on three postulates, which successfully explained the discrete line spectrum of hydrogen. According to the model, the radius of the nth stationary orbit is r_n ∝ n², and the total energy is E_n = −13.6 eV / n², when an electron jumps from a higher energy level (E_i) to a lower one (E_f), a photon of energy hν = E_i − E_f is emitted. Transitions ending at the n = 1 level form the Lyman series. According to Bohr's second postulate, which quantity is quantized?(a) Energy of electron(b) Orbital angular momentum(c) Linear momentum(d) Frequency of revolution
›Reveal solutionSolution
Bohr's second postulate quantizes the electron's orbital angular momentum in integer multiples of h/2π.
Bohr's second postulate states that an electron can revolve only in those orbits for which its orbital angular momentum is an integral multiple of ℏ=h/2π:
mvr=2πnh,n=1,2,3,…
✓Final answerOrbital angular momentum is the quantized quantity (option b).
- CBSE 2025Set ANNUAL1 markMCQQ.According to Bohr's hypothesis the following physical quantity is quantised(a) angular momentum(b) angular velocity(c) potential energy(d) momentum
›Reveal solutionSolution
Bohr's key postulate (beyond classical mechanics) was that only orbits where the electron's angular momentum is an integer multiple of h/2π are allowed.
Bohr's second postulate states that the electron can revolve only in those orbits for which its orbital angular momentum is an integral multiple of h/2π:
L=mvr=2πnh,n=1,2,3,…
This quantisation condition (not present in classical Rutherford's planetary model) is what restricts the electron to discrete stable orbits and discrete energy levels.
✓Final answer(a) angular momentum.
- CBSE 2025Set ANNUAL1 markMCQQ.The radius of Bohr's stable orbit for hydrogen is r. The radius of Bohr's second orbit is(a) r(b) r/2(c) 2r(d) 4r
›Reveal solutionSolution
In the Bohr model, the radius of the nth orbit of hydrogen scales as n^2, so if the (first, ground-state) orbit has radius r, the second orbit has radius 4r.
Bohr's model gives the radius of the nth stationary orbit of hydrogen as:
r_n = n^2 r_1
where r_1 is the radius of the first (n=1) orbit. Taking the given "stable orbit" radius r to be r_1, the second orbit (n=2) has radius:
r_2 = (2)^2 r_1 = 4r
This n^2 dependence comes from combining Bohr's quantization of angular momentum (mvr = nh/2-pi) with the Coulomb force providing the centripetal force.
✓Final answer(d) 4r.
- CBSE 2025Set ANNUAL1 markQ.If radius of first electron orbit of hydrogen is r0, radius of second electron orbit of hydrogen is ______.
›Reveal solutionSolution
In the Bohr model, the radius of the nth orbit of hydrogen scales as rn=n2r0, where r0 is the first-orbit (Bohr) radius.
Bohr's model gives the radius of the nth stationary orbit of the hydrogen atom as
rn=n2r0
where r0≈0.529 A˚ is the radius of the first orbit (n = 1). This follows from equating the Coulomb force to the centripetal force together with Bohr's quantization condition on angular momentum, mvr=n2πh.
For the second orbit, n = 2:
r2=22r0=4r0
✓Final answerr2=4r0.
- CBSE 2024Set ANNUAL1 markQ.If the radius of first orbit of hydrogen atom is 0.5 x 10^-10 m, then the radius of its second orbit will be __________ m.
›Reveal solutionSolution
Bohr's model gives orbit radius proportional to n², so the second orbit's radius is 2² = 4 times the first orbit's radius.
In Bohr's model of the hydrogen atom, the radius of the nth orbit is:
rn=n2r1
where r1 is the radius of the first (ground state) orbit. Given r1=0.5×10−10 m, for the second orbit (n=2):
r2=22×r1=4×0.5×10−10=2×10−10 m
✓Final answer2 × 10^-10 m.
- CBSE 2024Set ANNUAL1 markQ.What is Bohr's quantisation condition for the angular momentum of an electron in the second orbit ?
›Reveal solutionSolution
Bohr's second postulate: angular momentum is quantised as L=2πnh; for the second orbit, n=2.
Bohr's quantisation condition states that an electron can revolve only in those orbits for which its orbital angular momentum is an integral multiple of h/2π:
L=mvr=2πnh,n=1,2,3,…
For the second orbit, n=2:
L=2π2h=πh
✓Final answerL=2π2h=πh.
- CBSE 2023Set 55/1/11 markMCQQ.The radius of the nth orbit in Bohr model of hydrogen atom is proportional to :(a) n21(b) n1(c) n2(d) n
›Reveal solutionSolution
In the Bohr model, the electron's orbit radius grows with the principal quantum number because higher orbits require more angular momentum and lower electrostatic attraction. The radius is proportional to n2.
The Bohr model treats the hydrogen atom as a miniature solar system where the electron orbits the nucleus in circular paths. But unlike planets, the electron can only occupy certain allowed orbits, determined by quantum conditions. The question asks how the orbital radius scales with the quantum number n.
The key insight is that two forces govern the electron's motion: the electrostatic attraction pulling it inward and the requirement that its angular momentum be quantized. Let me show you how these constraints lead to the radius formula.
The physics behind the orbit
For a stable circular orbit, the centripetal force must equal the electrostatic force:
rmv2=r2ke2
where m is the electron mass, v its speed, k is Coulomb's constant, and e the electron charge. This gives us one equation relating r and v.
Bohr's quantum condition provides the second equation. He postulated that angular momentum is quantized:
mvr=nℏ
where ℏ=2πh and n=1,2,3,… is the principal quantum number.
Deriving the radius dependence
- From the angular momentum condition, solve for v:
v=mrnℏ
- Substitute this into the force balance equation:
rm(mrnℏ)2=r2ke2
- Simplify the left side:
m2r3m⋅n2ℏ2=mr3n2ℏ2=r2ke2
- Multiply both sides by r3:
mn2ℏ2=ke2r
- Solve for r:
r=mke2n2ℏ2
Everything on the right except n2 is a constant (fundamental constants of nature). Therefore:
rn∝n2
The proportionality constant is the Bohr radius a0=mke2ℏ2≈0.529 Å, so rn=n2a0.
Physical interpretation
Why does the radius grow as n2 and not linearly? As n increases, the electron must carry more angular momentum (∝n). But angular momentum is mvr, and the velocity actually decreases in higher orbits (the electron is less tightly bound). To compensate for the slower speed while maintaining higher angular momentum, the radius must increase faster than n — specifically, as n2.
Watch outDon't confuse this with the energy levels, which go as En∝−n21. The radius grows while the (negative) energy increases toward zero.
✓Final answerThe correct option is (c) n2.
- CBSE 2023Set ANNUAL1 markQ.Write the mathematical form of Bohr's postulate regarding angular momentum of electron in atom. (Write the answer only)
›Reveal solutionSolution
Bohr's second postulate states that the angular momentum of the electron in a stationary orbit is an integral multiple of h/2π.
Bohr postulated that an electron can revolve only in those orbits for which its orbital angular momentum is quantized:
L=mvr=2πnh,n=1,2,3,…
where m is the electron mass, v its orbital speed, r the orbit radius, h Planck's constant, and n the principal quantum number. Only orbits satisfying this condition are 'allowed' (stable, non-radiating) orbits.
✓Final answermvr=nh/2π.
- CBSE 2023Set ANNUAL1 markMCQQ.The Bohr model of atoms(1) assumes that the angular momentum of electrons is quantized(2) uses Einstein's photoelectric equation(3) predicts continuous emission spectra for atoms(4) predicts the same emission spectra for all types of atoms
›Reveal solutionSolution
Bohr's central postulate was that electrons can only occupy orbits where angular momentum is an integer multiple of h/2π.
Bohr postulated that an electron revolves only in those orbits for which its angular momentum is quantized: L=mvr=2πnh, n=1,2,3,…. This quantization condition (not option b, which is unrelated to Bohr's model; and not options c/d, since Bohr's model correctly predicts DISCRETE, atom-specific line spectra, not continuous or universal ones) is the defining feature of the Bohr model.
✓Final answer(1) assumes that the angular momentum of electrons is quantized.
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