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Exercises · 10.3

Q.Why are alkali metals not found in nature ?

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✓ Free question

Step 1: Note their electronic structure

Alkali metals have the configuration ns1^1, meaning just one loosely-held valence electron outside a stable noble-gas core.

Step 2: Consequence — very low ionisation enthalpy

This single electron is very easily lost, giving alkali metals the lowest ionisation enthalpies of any group, and making them extremely strong reducing agents and highly electropositive.

Step 3: Consequence — extreme reactivity

As a result they react vigorously and spontaneously with atmospheric moisture, oxygen, and carbon dioxide, and violently with water, immediately converting the free metal into oxides, hydroxides or carbonates.

Step 4: Conclusion

Because any free metal is converted to a compound almost instantly under normal environmental conditions, alkali metals are never found in the elemental (native) state in nature; they occur only as stable, combined compounds such as chlorides (e.g. NaCl in seawater and rock salt), silicates and other minerals.

✓Final answer

Alkali metals are not found free in nature because their very low ionisation enthalpy makes them intensely reactive, reducing agents that instantly combine with moisture, O2_2 and CO2_2; they exist only as compounds (chlorides, silicates, carbonates, etc.).

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