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Q.Compare isothermal and an adiabatic process.

Telangana TsbieTelangana Board of Intermediate Education (Intermediate 1st Year) 2022Subjective· 4mImportance★★★★★
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Isothermal and adiabatic processes differ mainly in heat exchange: isothermal keeps temperature fixed by exchanging heat freely; adiabatic allows no heat exchange, so temperature itself changes.

FeatureIsothermal processAdiabatic process
TemperatureRemains constant (ΔT = 0)Changes during the process
Heat exchangeHeat freely exchanged with surroundings (ΔQ ≠ 0)No heat exchange with surroundings (ΔQ = 0)
Governing equationPV = constant (Boyle's law, since T fixed)PV^γ = constant, where γ = Cp/Cv
Walls/conditionsOccurs through thermally conducting walls, and/or very slowly, so the system stays in thermal equilibrium with surroundingsOccurs through thermally insulated (non-conducting) walls, and/or very rapidly, so no time for heat exchange
First law formΔQ = ΔW (since ΔU = 0 for an ideal gas at constant T)ΔW = −ΔU (work is done entirely at the expense of internal energy, or vice versa)
Molar heat capacityInfinite (heat can be absorbed with no temperature rise)Zero (no heat is absorbed at all)
Slope on P–V diagramLess steep: dP/dV = −P/VSteeper: dP/dV = −γP/V (steeper by factor γ, since γ > 1)
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