Skip to content

Physics · Ch 3 — Current Electricity

Temperature Dependence of Resistivity

3.8

Temperature Dependence of Resistivity

Why Does Resistivity Change with Temperature?

Resistivity (ρ\rho) is not a fixed property of a material — it changes with temperature. The way it changes depends on the type of material: metals, alloys, and semiconductors behave differently. The physical reason lies in the microscopic picture of current flow.

The Approximate Linear Relation (for Metals)

Over a limited range of temperature (not too large), the resistivity of a metallic conductor follows a simple linear law. If you know the resistivity ρ0\rho_0 at some reference temperature T0T_0, then the resistivity ρT\rho_T at another temperature TT is given by:

ρT=ρ0[1+α(T−T0)]\rho_T = \rho_0 [1 + \alpha (T - T_0)]

  • ρT\rho_T = resistivity at temperature TT
  • ρ0\rho_0 = resistivity at reference temperature T0T_0
  • α\alpha = temperature coefficient of resistivity (unit: ∘C−1^\circ\text{C}^{-1} or K−1\text{K}^{-1})
  • T−T0T - T_0 = change in temperature

For metals, α\alpha is positive — resistivity increases as temperature rises.

Important: This formula gives a straight line when ρT\rho_T is plotted against TT, but it is only an approximation. At very low temperatures (much below 0∘C0^\circ\text{C}), the graph deviates significantly from a straight line.

Special Materials: Alloys with Weak Temperature Dependence

Some alloys show a very weak dependence of resistivity on temperature. Examples include:

  • Nichrome (nickel, iron, chromium)
  • Manganin
  • Constantan

Because their resistance changes very little with temperature, these materials are used to make wire-bound standard resistors — components that need a stable, predictable resistance.

The Opposite Behaviour: Semiconductors

Unlike metals, the resistivity of semiconductors decreases as temperature increases. This is the opposite of what metals do.

Physical Explanation: Why Does This Happen?

The resistivity formula derived earlier is:

ρ=1σ=mne2τ\rho = \frac{1}{\sigma} = \frac{m}{n e^2 \tau}

Where:

  • mm = mass of electron
  • nn = number of free electrons per unit volume
  • ee = charge of electron
  • τ\tau = average time between collisions (relaxation time)

Resistivity ρ\rho depends on two key factors:

  1. nn — the density of charge carriers
  2. τ\tau — how long electrons travel before colliding
In Metals: …
Figure 3.8Resistivity ρ_T of copper as a function of temperature T.
Fig. 3.8 — Resistivity ρ_T of copper as a function of temperature T.

Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.

The graph plots resistivity ρT\rho_T (in units of 10−8 Ω m10^{-8} \, \Omega \, \text{m}) on the vertical axis against absolute temperature TT (in kelvin) on the horizontal axis. The vertical axis is marked at 0.20.2 and 0.40.4 (i.e., 0.2×10−8 Ω m0.2 \times 10^{-8} \, \Omega \, \text{m} and 0.4×10−8 Ω m0.4 \times 10^{-8} \, \Omega \, \text{m}). The horizontal axis has ticks at 00, 5050, 100100, and 150150 K.

The curve begins near the origin at very low temperatures and rises with an upward-concave (parabola-like) shape. By T≈150T \approx 150 K, the resistivity climbs steeply toward ρ≈0.4×10−8 Ω m\rho \approx 0.4 \times 10^{-8} \, \Omega \, \text{m}. This shows that resistivity increases with temperature for copper, but the increase is not linear over the entire range — especially at very low temperatures, the graph deviates from a straight line.

Physical idea: Over a limited range of temperatures (not too large), the resistivity of a metallic conductor follows the approximate linear relation:

ρT=ρ0[1+α(T−T0)]\rho_T = \rho_0 \left[ 1 + \alpha (T - T_0) \right]

where:

  • ρT\rho_T = resistivity at temperature TT,
  • ρ0\rho_0 = resistivity at a reference temperature T0T_0,
  • α\alpha = temperature coefficient of resistivity (units: ∘C−1^\circ\text{C}^{-1} or K−1\text{K}^{-1}).

For metals, α\alpha is positive, meaning resistivity rises with temperature. However, at temperatures much lower than 0∘C0^\circ\text{C} (i.e., below about 273 K), the graph deviates considerably from a straight line — as Fig. 3.8 shows with its curved shape near the origin. The linear formula is therefore only an approximation valid over a limited range around any chosen T0T_0. …

Figure 3.9Resistivity ρ_T of nichrome as a function of absolute temperature T.
Fig. 3.9 — Resistivity ρ_T of nichrome as a function of absolute temperature T.

Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.

The graph plots resistivity ρT\rho_T (in units of μΩ cm\mu\Omega\,\text{cm}) on the vertical axis against absolute temperature TT (in kelvin) on the horizontal axis. The vertical scale runs from 1.001.00 to 1.20 μΩ cm1.20\ \mu\Omega\,\text{cm}, and the horizontal scale from 200200 to 800 K800\ \text{K}.

The data form a nearly straight line with a gentle positive slope. At low temperatures (near 200 K200\ \text{K}) the resistivity is about 1.08 μΩ cm1.08\ \mu\Omega\,\text{cm}, rising to about 1.20 μΩ cm1.20\ \mu\Omega\,\text{cm} at 800 K800\ \text{K}. This weak, almost-linear increase contrasts sharply with the curved plot for copper shown in the textbook’s Fig. 3.8.

Physical idea: Nichrome is an alloy (nickel, iron, chromium) whose resistivity changes very little with temperature. This makes it ideal for wire-wound standard resistors and heating elements, because its resistance remains nearly constant over a wide temperature range.

Key formula developed with this figure is the linear approximation for resistivity over a limited temperature range:

ρT=ρ0[1+α(T−T0)]\rho_T = \rho_0 \left[ 1 + \alpha (T - T_0) \right]

  • ρT\rho_T = resistivity at temperature TT
  • ρ0\rho_0 = resistivity at reference temperature T0T_0
  • α\alpha = temperature coefficient of resistivity (units: ∘C−1^\circ\text{C}^{-1} or K−1\text{K}^{-1}) …
Figure 3.10Temperature dependence of resistivity for a typical semiconductor.
Fig. 3.10 — Temperature dependence of resistivity for a typical semiconductor.

Drawn by us to help you understand the concept clearly, and verified to make sure it's accurate. For exams, practice from your textbook's own diagram.

What the Graph Shows

The figure is a first-quadrant plot with resistivity ρ\rho on the vertical axis and temperature TT on the horizontal axis. There are no numeric ticks — it is a schematic (conceptual) graph.

The curve begins at a high value of ρ\rho when TT is small (near the vertical axis). As TT increases, the curve falls steeply, then gradually flattens out and approaches the TT-axis asymptotically. The shape is that of an exponential decay: resistivity decreases rapidly at first, then more slowly, and eventually tends toward a very low, nearly constant value.

The Physical Idea

This graph illustrates the opposite behaviour of semiconductors compared to metals. For metals, resistivity increases with temperature (positive temperature coefficient). For semiconductors, resistivity decreases with temperature (negative temperature coefficient).

The reason lies in the number of charge carriers nn. In a semiconductor, raising the temperature dramatically increases nn — more electrons break free from their bonds and become available for conduction. This increase in nn more than compensates for the decrease in the average collision time τ\tau (which also occurs because electrons move faster). The net effect is that ρ\rho drops sharply.

The Key Formula

The textbook derives resistivity from the relation:

ρ=1σ=mne2τ\rho = \frac{1}{\sigma} = \frac{m}{n e^2 \tau}

where:

  • mm = mass of an electron
  • nn = number of free electrons per unit volume …