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Chemistry · Class 11 Science

Ch 6s-Block Elements — Class 11 Chemistry, concept-first.

Group 1 of the periodic table -- lithium, sodium, potassium, rubidium, caesium and francium -- is called the alkali metal family because their hydroxides are strong alkalis (bases) that dissolve freely in water.

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6.1

Introduction

Group 1 of the periodic table -- lithium, sodium, potassium, rubidium, caesium and francium -- is called the alkali metal family because their hydroxides are strong alkalis (bases) that dissolve freel…

6.2

Electronic Configuration and Occurrence of Group 1 and Group 2 Elements

Group 1: general electronic configuration. Every alkali metal atom has the configuration of the preceding noble gas plus one additional electron in the outermost s orbital, written generally as : lith…

6.3

Periodic Trends: Atomic and Ionic Radii, Ionization Enthalpy

Atomic and ionic radii. On descending either group, one full principal quantum shell is added at every step, so both the atomic radius and the ionic radius increase steadily and substantially down the…

6.4

Chemical Reactivity of Alkali Metals

Alkali metals are the most chemically reactive of all metals, on account of their very low ionization enthalpies, and this reactivity increases steadily on descending the group from lithium to caesium…

6.5

Chemical Reactivity of Alkaline Earth Metals

Alkaline earth metals are also highly reactive, though as a rule less reactive than the alkali metal of the same period, since their higher ionization enthalpy makes them somewhat less ready to lose e…

6.6

Classification of Hydrides: Ionic, Covalent and Interstitial

When hydrogen combines with another element, the compound formed -- a hydride -- can fall into any of three structurally very different classes, depending chiefly on the electronegativity, size and el…

6.7

Hydrogen Peroxide: Preparation, Structure and Properties

Hydrogen peroxide, , is a pale blue, syrupy liquid, completely miscible with water, and one of the most important industrial oxidizing/bleaching agents.

6.8

Hydrogen as a Fuel

Burning dihydrogen releases an unusually large amount of energy for its mass -- more energy per kilogram than any conventional fossil fuel -- and its combustion produces only water, with no carbon dio…

6.9

Biological Importance of Sodium, Potassium, Magnesium and Calcium

Four s-block elements -- sodium, potassium, magnesium and calcium -- are essential (biologically indispensable) elements, each with a distinct, well-established physiological role.

Summary

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  1. Example 1Write the general outer electronic configuration of the Group 1 (alkali metal) elements and use it to name all six elements of the group.Free
  2. Example 2Write the general outer electronic configuration of the Group 2 (alkaline earth metal) elements and name all six elements of the group.Free
  3. Example 3Name the principal ores in which lithium, sodium and potassium occur in nature, giving the formula of each.Free
  4. Example 4Name the principal ores in which magnesium and calcium occur in nature, giving the formula of each.Preview
  5. Example 5Arrange Li, Na, K, Rb and Cs in order of increasing first ionization enthalpy and explain the trend.Preview
  6. Example 6Explain why the atomic radius and the ionic radius both increase steadily on descending Group 1 from Li to Cs.Preview
  7. Example 7For the same period, is the first ionization enthalpy of a Group 2 element higher or lower than that of the neighbouring Group 1 element? Ex…Preview
  8. Example 8Write balanced equations for the products formed when (a) lithium and (b) sodium are burnt in an excess supply of dry oxygen.Preview
  9. Example 9Potassium burns in excess oxygen to form a superoxide rather than a normal oxide or a peroxide. Write the balanced equation and explain why…Preview
  10. Example 10Write the general equation for the reaction of an alkali metal with water and explain why the vigour of this reaction increases from lithium…Preview
  11. Example 11Write the equation for the reaction of sodium with dihydrogen gas and name the type of hydride formed.Preview
  12. Example 12Write the equation for the reaction of potassium with chlorine gas and state the nature of the bond in the product.Preview
  13. Example 13Write the balanced equation for the burning of magnesium ribbon in air, naming both products formed.Preview
  14. Example 14Write the balanced equation for the reaction of calcium metal with cold water and describe what is observed.Preview
  15. Example 15Beryllium does not react with water even at red heat, unlike the other Group 2 metals. Explain why.Preview
  16. Example 16Write the equation for the formation of calcium hydride from calcium metal and dihydrogen, and state why beryllium does not form an analogou…Preview
  17. Example 17Write the equation for the reaction of magnesium with chlorine gas, and comment on the nature of the bonding in magnesium chloride compared…Preview
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  1. Q18Classify each of the following as an ionic, a covalent or an interstitial hydride, giving a reason in each case: (a) $\text{NaH}$, (b) $\tex…Free
  2. Q19What are interstitial (metallic) hydrides? Explain why they have a non-stoichiometric composition and why the parent metal retains its metal…Free
  3. Q20Describe, with equations, the industrial preparation of hydrogen peroxide by (a) the electrolytic oxidation of a bisulfate solution and (b)…Free
  4. Q21Describe the molecular structure of hydrogen peroxide and explain what is meant by calling it an "open book" or "skew" structure.Preview
  5. Q22Hydrogen peroxide can act both as an oxidizing agent and as a reducing agent. Illustrate each behaviour with one balanced ionic equation.Preview
  6. Q23List four practical uses of hydrogen peroxide, explaining briefly the chemical property being exploited in each case.Preview
  7. Q24Explain why hydrogen is regarded as a promising fuel of the future, and distinguish between burning hydrogen directly and using it in a hydr…Preview
  8. Q25Explain the biological role of $\text{Na}^+$ and $\text{K}^+$ ions in the transmission of a nerve impulse.Preview
  9. Q26Describe two distinct biological roles each of magnesium and calcium in the human body/plants.Preview