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Exercise · Q22

Q.Hydrogen peroxide can act both as an oxidizing agent and as a reducing agent. Illustrate each behaviour with one balanced ionic equation.

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Concept understanding — Hydrogen Peroxide

Hydrogen Peroxide

Hydrogen peroxide H2O2\text{H}_2\text{O}_2 is a pale-blue, syrupy liquid that is miscible with water in all proportions (not immiscible) and has a non-planar open-book structure.

Redox behaviour: the oxygen is in the –1 state, so H2O2\text{H}_2\text{O}_2 can act as both an oxidising and a reducing agent in acidic and basic media. With acidified K2Cr2O7\text{K}_2\text{Cr}_2\text{O}_7 it gives blue chromium peroxide CrO5\text{CrO}_5 (or CrO(O2)2\text{CrO(O}_2)_2), which is extracted into the ethereal layer as a blue colour — a classic test. …

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