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Example · Example 17

Q.Write the equation for the reaction of magnesium with chlorine gas, and comment on the nature of the bonding in magnesium chloride compared with beryllium chloride.

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Magnesium combines directly with chlorine gas to form magnesium chloride:

Mg+Cl2⟶MgCl2\text{Mg} + \text{Cl}_2 \longrightarrow \text{MgCl}_2

Because Mg2+\text{Mg}^{2+}, though smaller than the alkali-metal or heavier alkaline-earth cations, is still large enough not to distort the chloride ion's electron cloud too severely, magnesium chloride is predominantly an ionic compound.

Beryllium chloride, BeCl2\text{BeCl}_2, behaves quite differently. The Be2+\text{Be}^{2+} ion is exceptionally small and carries a high charge density, so it polarizes the chloride ion strongly enough to give the Be-Cl bond substantial covalent character. As a direct structural consequence, solid BeCl2\text{BeCl}_2 does not form a simple ionic lattice like MgCl2\text{MgCl}_2 but instead exists as a chain polymer, with chlorine atoms bridging between beryllium centres -- a structural pattern closely paralleling the covalent, bridged structure of alumin …

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