Q.Define degrees of freedom. Write down the principle of equipartition of energy. Find the value of γ (= Cp/Cv) of a diatomic gas. OR Show that for ideal gas Cp - Cv = R and γ = 1 + 2/f, where f is the degrees of freedom of the molecule.

Degrees of Freedom: The Intuition

Imagine you are standing in an empty room. You can walk forward and backward, slide left and right, and even jump up and down. That is three independent ways to change your position. Now, if you were a tiny ant crawling on a sheet of paper, you could only move forward/backward and left/right — you cannot jump off the paper. That is two independent ways. If you were a bead on a wire, you can only slide along the wire — one way.

That number — the count of independent ways something can move or change — is its degrees of freedom.

The Precise Statement

Degrees of freedom of a system is the minimum number of independent coordinates (or parameters) needed to completely specify its configuration — that is, the position and orientation of every part of the system — at any instant.

For a single particle moving in 3D space, you need three numbers: $(x, y, z)$. So it has 3 degrees of freedom.

For a rigid body (like a brick, not a squishy ball), you need:

• 3 coordinates to fix its centre of mass (where it is in space)
• 3 angles to fix its orientation (how it is rotated — pitch, yaw, roll)

That gives 6 degrees of freedom for a free rigid body.

Why This Matters in Exams

The concept appears in two main places:

1. Statistical Mechanics / Kinetic Theory of Gases — The energy of a gas molecule is shared equally among its degrees of freedom (equipartition theorem). A monatomic gas (like helium) has 3 translational degrees of freedom. A diatomic gas (like oxygen) has 3 translational + 2 rotational = 5 at ordinary temperatures. Each degree of freedom contributes $\frac{1}{2}kT$ to the internal energy per molecule.

2. Mechanics / Vibrations — The number of degrees of freedom tells you how many independent equations of motion you need. A pendulum has 1 degree of freedom (the angle). A double pendulum has 2. A continuous string has infinitely many. …