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Example · Example 7

Q.Find the total number of degrees of freedom of

(a) a monatomic gas molecule,
(b) a rigid diatomic gas molecule at moderate temperature (ignoring vibration), and
(c) a non-linear triatomic gas molecule.
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  1. Monatomic. A single point-like atom has only translational motion along the three perpendicular axes xx, yy, zz: f=3f = 3.
  2. Rigid diatomic (vibration ignored). Besides the same 33 translational degrees of freedom, the molecule can rotate about the 22 axes perpendicular to the bond axis (rotation about the bond axis itself contributes negligible energy, since the atoms sit essentially on that axis). Total: f=3+2=5f = 3+2 = 5. …

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