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Question 38 of 43

Q.IUPAC name of the compound H3C-CH(OCH3)-CH3 (isopropyl methyl ether, i.e. CH3 attached to a CH bearing OCH3 and another CH3) is

(a) 1-methoxy-1-methyl ethane
(b) 2-methoxy-2-methyl ethane
(c) Isopropyl methyl ether
(d) 2-methoxypropane
West Bengal WbchseWest Bengal HS (WBCHSE) Board 2025MCQ· 1mImportance★★★★★
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The compound is an ether; IUPAC names an ether as an alkoxy-substituted alkane, giving 2-methoxypropane.

The compound CH3CH_3-CH(OCH3)CH(OCH_3)-CH3CH_3 is isopropyl methyl ether. In IUPAC substitutive nomenclature, an ether RR-OO-R′R' is named by treating the smaller −OR′-OR' group as an alkoxy substituent on the longer alkyl chain RR.

Here the parent chain is propane (CH3CH_3-CH2CH_2-CH3CH_3 skeleton, 3 carbons), and the −OCH3-OCH_3 (methoxy) group is attached at carbon 2 of that chain (the central CH). So the systematic name is 2-methoxypropane.

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