Q.Explain why the carbonyl carbon of an aldehyde or ketone is electrophilic, using the polarity of the bond and the hybridisation of the carbon.
The carbonyl carbon is hybridised, forming three coplanar bonds at and one bond to oxygen from its remaining unhybridised orbital. Because oxygen is considerably more electronegative than carbon, it attracts the (and to a lesser extent ) bonding electrons more strongly, leaving the oxygen with a partial negative charge () and the carbon with a matching partial positive charge (). This can be represented by a minor charge-separated resonance form, , alongside the major neutral form.
The planar, carbonyl carbon carries a partial positive charge because the more electronegative oxygen pulls the electron density towards itself, making the carbon electron-deficient and open to nucleophilic attack from either face.
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