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Example · Example 29

Q.Give the IUPAC name of CH3CH2CH(Cl)COOH\text{CH}_3\text{CH}_2\text{CH}(\text{Cl})\text{COOH} and identify the locant given to the carboxyl carbon.

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The longest chain containing the -COOH\text{-COOH} group is four carbons (but-), and the carboxyl carbon is, by definition, always numbered C-1 -- it needs no locant of its own in the name, only the '-oic acid' suffix. Counting along the chain from C-1, the chlorine substituent sits on the second carbon, giving the name 2-chl …

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