Exercise · Q4
Q.The bond length in formaldehyde () is shorter than a typical single bond. Explain this using the bonding picture of the carbonyl group (one and one bond) and state the shape around the carbonyl carbon.
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✓ Free question
A single bond involves only one shared electron pair (a bond); the carbonyl bond additionally has a bond formed by sideways overlap of unhybridised orbitals on carbon and oxygen. This second bond pulls the two nuclei measurably closer together, which is why () is shorter than () -- exactly analogous to why is shorter than . The carbonyl carbon itself is hybridised, so it and its three attached atoms all lie in one plane with bond angles close to .
✓Final answer
The extra bond present in (absent in a single bond) shortens the bond, and the carbonyl carbon is trigonal planar (, bond angles).
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