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Question 48 of 49

Q.Glucose and fructose can be distinguished by which of the following reagents?

(a) Tollen's reagent
(b) Fehling's reagent
(c) Br2 / H2O
(d) C6H5-NH-NH2
West Bengal WbchseWest Bengal HS (WBCHSE) Board 2026MCQ· 1mImportance★★★★★
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Br2/H2O is a mild oxidant that oxidises only aldoses; glucose (aldose) reacts, fructose (ketose) does not, so bromine water distinguishes them. Correct option (c).

Glucose is an aldohexose (has -CHO), fructose is a ketohexose (has >C=O). Bromine water is a mild oxidising agent specific to the aldehyde group: it oxidises glucose's -CHO to -COOH (gluconic acid, decolourising the bromine), but it cannot oxidise fructose's keto group. So Br2/H2O gives a positive result only with glucose.

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