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Example · Example 1

Q.Classify glucose and fructose as an aldose or a ketose, and explain the basis of this classification.

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✓ Free question

A monosaccharide's classification as an aldose or a ketose depends purely on the position and type of its carbonyl group. Glucose's open-chain structure has an aldehyde group, −CHO-\text{CHO}, at carbon C1 (the very end of the chain), so glucose is classified as an aldose -- and, since it has six carbons, more precisely as an aldohexose. Fructose's open-chain structure instead has a ketone carbonyl group, C=O\text{C}{=}\text{O}, at carbon C2, one carbon in from the end, so fructose is classified as a ketose -- again, with six carbons, a ketohexose. Both share the molecular formula C6H12O6\text{C}_6\text{H}_{12}\text{O}_6 and differ only in where and what kind of carbonyl group they carry.

✓Final answer

Glucose is an aldohexose (aldehyde carbonyl at C1); fructose is a ketohexose (ketone carbonyl at C2).

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