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Example · Example 2

Q.Write the open-chain (Fischer projection) structure of D-glucose and identify all the functional groups present in it.

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Numbering the six carbons from the aldehyde end, D-glucose's open-chain (Fischer projection) structure is: C1 −CHO-\text{CHO} (aldehyde), C2 −OH-\text{OH} on the right, C3 −OH-\text{OH} on the left, C4 −OH-\text{OH} on the right, C5 −OH-\text{OH} on the right, and C6 the terminal −CH2OH-\text{CH}_2\text{OH}. Written in condensed form: CHO−(CHOH)4−CH2OH\text{CHO}{-}(\text{CHOH})_4{-}\text{CH}_2\text{OH}.

Counting functional groups: there is exactly one aldehyde group (−CHO-\text{CHO}, at C1) and five hydroxyl groups (−OH-\text{OH}, at C2, C3, C4, C5 and the primary −OH-\text{OH} of C6), for a total molecular formula of C6H12O6\text{C}_6\text{H}_{12}\text{O}_6.

✓Final answer

D-glucose has one aldehyde group (C1) and five hydroxyl groups (C2-C6), giving the formula C6H12O6\text{C}_6\text{H}_{12}\text{O}_6.

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