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Q.Give two differences in between Double Salt and Complex Salt. OR Give two fundamental differences in between Nucleoside and Nucleotide.

West Bengal WbchseWest Bengal HS (WBCHSE) Board 2022Subjective· 2mImportance★★★★★
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Double salts break apart completely into simple ions in solution (giving normal ion tests); complex salts contain a complex ion that stays intact in solution (failing the normal metal-ion test).

Difference 1 — Behaviour in solution:

A double salt, e.g. Mohr's salt FeSO4.(NH4)2SO4.6H2O or potash alum KAl(SO4)2.12H2O, dissociates completely in water into all its simple constituent ions (Fe2+, NH4+, SO4^2- for Mohr's salt), each of which gives its characteristic chemical test.

A complex salt, e.g. K4[Fe(CN)6] (potassium ferrocyanide), dissociates in water to give K+ ions and the complex ion [Fe(CN)6]^4-, but the complex ion itself does NOT further dissociate into Fe2+ and CN- ions. Hence it fails to give the usual test for Fe2+ (no blue colour with K3[Fe(CN)6], etc.) and gives only a very weak/no test for free CN-.

Difference 2 — Stability/existence:

Double salts are stable and retain their identity only in the crystalline (solid) state; once dissolved they lose that identity and behave as a simple mixture of ions. …

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