Q.Explain Brownian movement, state its physical cause, and explain how it contributes to the stability of a colloidal solution against settling under gravity.
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Start your 14-day free trial to unlock the full solution →Brownian movement is the continuous, random, zig-zag motion of colloidal particles observed under a microscope, first reported by Robert Brown. Its physical cause is the constant bombardment of each (comparatively large and heavy) colloidal particle by the vastly more numerous, much smaller, and extremely fast-moving molecules of the dispersion medium; because this bombardment is never perfectly equal from every direction at a given instant, the particle receives a net, randomly-changing push, producing its erratic path. This ceaseless agitation works continuously against the tendency of colloidal particles to settle under gravity, and is one of the principal reasons a lyophobic colloid, despite not being thermodynamically stable, remains kinetically stable — i.e. remains dispersed indefinitely rather than settling …
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