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Exercise · Q18

Q.Bakelite is prepared by the condensation of phenol with formaldehyde. Name the linear intermediate formed before cross-linking, and describe the role formaldehyde plays in forming the final resin.

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When phenol is condensed with a LIMITED amount of formaldehyde under acidic catalysis, the reaction stops at a linear, low-molecular-weight, still-fusible prepolymer called novolac (a base-catalysed, formaldehyde-excess route instead gives a partially cross-linked prepolymer called resole). In either case, this intermediate still carries reactive −CH2OH-\text{CH}_2\text{OH} groups and open, unreacted ring positions. On curing (heating, usually with additional formaldehyde as a cross-linking agent and a hardener), formaldehyde's role shifts from simply extending single chains to actively BRIDGING separate chains: it reacts with the reactive sites on neighbouring novolac/resole chains to form methylene (−CH2−-\text{CH}_2-) bridges linking many phenol rings together in three dimensions, …

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