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Worked Examples · Example 1.12

Q.An early model for an atom considered it to have a positively charged point nucleus of charge ZeZe, surrounded by a uniform density of negative charge up to a radius RR. The atom as a whole is neutral. For this model, what is the electric field at a distance rr from the nucleus?

Figure 1.29
Figure 1.29
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We use Gauss's Law to find the electric field in two regions: inside and outside the negative charge cloud. The field is zero outside the atom, and inside, it is E=Ze4πϵ0(1r2−rR3)r^\mathbf{E} = \frac{Ze}{4\pi \epsilon_0} \left(\frac{1}{r^2} - \frac{r}{R^3}\right) \hat{r}.

The problem describes an early atomic model with a point nucleus of charge ZeZe at the center, surrounded by a uniformly distributed negative charge cloud up to a radius RR. The atom as a whole is neutral. We need to find the electric field at a distance rr from the nucleus.

This problem exhibits spherical symmetry. Whenever we have a spherically symmetric charge distribution, Gauss's Law is the most efficient tool to calculate the electric field. Gauss's Law states that the total electric flux through any closed surface (called a Gaussian surface) is proportional to the total electric charge enclosed within that surface.

∮E⃗⋅dA⃗=Qencϵ0\oint \vec{E} \cdot d\vec{A} = \frac{Q_{enc}}{\epsilon_0}

Here, E⃗\vec{E} is the electric field, dA⃗d\vec{A} is an infinitesimal area vector on the Gaussian surface, QencQ_{enc} is the total charge enclosed by the Gaussian surface, and ϵ0\epsilon_0 is the permittivity of free space. Due to spherical symmetry, the electric field E⃗\vec{E} will be radial, pointing outwards for positive enclosed charge and inwards for negative enclosed charge. Its magnitude will be constant on any spherical surface centered at the nucleus. Thus, for a spherical Gaussian surface of radius rr, the integral simplifies to E(4πr2)E(4\pi r^2).

We need to consider two distinct regions:

  1. Outside the atom: r>Rr > R
  2. Inside the negative charge cloud: r<Rr < R

Let's proceed step-by-step.

  1. Determine the total negative charge and its volume charge density. The atom as a whole is neutral. Since the nucleus has a positive charge ZeZe, the total negative charge distributed in the cloud must be −Ze-Ze. This negative charge is uniformly distributed within a sphere of radius RR. The volume of this sphere is V=43πR3V = \frac{4}{3}\pi R^3. The uniform volume charge density ρ\rho of the negative charge cloud is:

ρ=Total negative chargeVolume=−Ze43πR3=−3Ze4πR3\rho = \frac{\text{Total negative charge}}{\text{Volume}} = \frac{-Ze}{\frac{4}{3}\pi R^3} = -\frac{3Ze}{4\pi R^3}

  1. Calculate the electric field for r>Rr > R (outside the atom). Consider a spherical Gaussian surface of radius rr such that r>Rr > R. This surface encloses the entire atom. The total charge enclosed, QencQ_{enc}, is the sum of the nucleus charge and the total negative charge cloud:

Qenc=Ze+(−Ze)=0Q_{enc} = Ze + (-Ze) = 0

Applying Gauss's Law:

∮E⃗⋅dA⃗=Qencϵ0\oint \vec{E} \cdot d\vec{A} = \frac{Q_{enc}}{\epsilon_0}

E(4πr2)=0ϵ0E (4\pi r^2) = \frac{0}{\epsilon_0}

E=0for r>RE = 0 \quad \text{for } r > R

This result makes sense: a neutral atom, when viewed from a distance much larger than its size, appears as a point charge of zero magnitude, hence producing no external electric field.

3. Calculate the electric field for r<Rr < R (inside the negative charge cloud).

Consider a spherical Gaussian surface of radius rr such that r<Rr < R.

The charge enclosed, QencQ_{enc}, by this Gaussian surface consists of two parts:

* The positive charge of the nucleus: ZeZe.

* The negative charge enclosed within the Gaussian sphere of radius rr.

The volume of the Gaussian sphere is Vr=43πr3V_r = \frac{4}{3}\pi r^3.

The negative charge enclosed, Qneg,encQ_{neg, enc}, is the product of the charge density ρ\rho and this volume:

Qneg,enc=ρ⋅Vr=(−3Ze4πR3)(43πr3)=−Zer3R3Q_{neg, enc} = \rho \cdot V_r = \left(-\frac{3Ze}{4\pi R^3}\right) \left(\frac{4}{3}\pi r^3\right) = -Ze \frac{r^3}{R^3}

Now, the total charge enclosed by the Gaussian surface is: …

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