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Using the data from the table given b... · Q27

Q.Using the same table (C2H6/C2H4/C2H2 bond length and bond enthalpy data): Which is the most stable compound?

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✓ Free question

Step 1. Read the table's bond-enthalpy column. C2H6: 348 kJ mol⁻¹. C2H4: 612 kJ mol⁻¹. C2H2: 837 kJ mol⁻¹.

Step 2. Apply the rule linking bond order/enthalpy to stability (sections 5.6.2, 5.6.4). A higher bond enthalpy means a stronger bond, which in turn means a more stable molecule (with respect to that particular bond breaking).

Step 3. Identify the highest value. C2H2's carbon-carbon triple bond has by far the largest bond enthalpy of the three (837 kJ mol⁻¹, vs 612 for C2H4's double bond and 348 for C2H6's single bond).

✓Final answer

C2H2 (ethyne), with the highest C-C bond enthalpy (837 kJ mol⁻¹), is the most stable of the three compounds with respect to breaking that carbon-carbon bond.

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