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Chemistry · Ch 4 — Structure of Atom

Electronic Configuration of Atoms and Its Representation

4.7.6

Electronic Configuration of Atoms and Its Representation

The electronic configuration of an atom is simply the distribution of its electrons among its available orbitals in the ground state, built up by applying the Aufbau principle (energy order, Pauli's principle and Hund's rule together). There are two standard ways to WRITE it down. Orbital notation strings together each occupied subshell as nsanpbndc…n s^{a} n p^{b} n d^{c}\ldots, where the superscript gives the number of electrons in that subshell (for example, 1s2 2s2 2p61s^2\,2s^2\,2p^6 for neon). Orbital-diagram notation instead draws a small box for every individual orbital in a subshell, with an up arrow (↑) or down arrow (↓) placed in a box to represent one electron of a particular spin; because it shows spins explicitly, the orbital-diagram form is the only one of the two that fully captures all four quantum numbers of every electron. For elements with a large atomic number, the plain orbital notation becomes a long string; this is shortened with a CONDENSED notation, which represents the electron configuration of the preceding noble gas — the 'core', identical for every element that follows it until the next noble gas — as that noble gas's symbol in square brackets, followed only by the 'outer' electrons specific to the element in question. Pot …

Table 4.11Representation of electronic configuration for sample elements

Table 4.11 — orbital notation for a few elements:

₁H: 1s¹.

₂He: 1s².

₃Li: 1s² 2s¹.

₄Be: 1s² 2s².

₉F: 1s² 2s² 2p⁵. …

Table 4.12Electronic configuration of the first thirty elements

Table 4.12 — condensed orbital notation of elements Z=1 to 30 (K, L, M, N shell filling):

1 H [1s¹]; 2 He [1s²]; 3 Li [He]2s¹; 4 Be [He]2s²; 5 B [He]2s²2p¹; 6 C [He]2s²2p²; 7 N [He]2s²2p³; 8 O [He]2s²2p⁴; 9 F [He]2s²2p⁵; 10 Ne [He]2s²2p⁶; 11 Na [Ne]3s¹; 12 Mg [Ne]3s²; 13 Al [Ne]3s²3p¹; 14 Si [Ne]3s²3p²; 15 P [Ne]3s²3p³; 16 S [Ne]3s²3p⁴; 17 Cl [Ne]3s²3p⁵; 18 Ar [Ne]3s²3p⁶; 19 K [Ar]4s¹; 20 Ca [Ar]4s²; 21 Sc [Ar]4s²3d¹; 22 Ti [Ar]4s²3d²; 23 V [Ar]4s²3d³; 24 Cr [Ar]4s¹3d⁵ (anomalous); 25 Mn [Ar]4s²3d⁵; 26 Fe [Ar]4 …

Misc Problem 4.11Electronic configuration of Ar and K

Worked out. Worked example: write the electronic configuration of ₁₈Ar and ₁₉K using both orbital notation and orbital diagram. Ar (18 electrons): 1s² 2s² 2p⁶ 3s² 3p⁶, filled boxes for 1s, 2s, 2p, 3s and 3p. K (19 electrons): 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹, the same as Ar's configuration plus one electron in a new 4s orbital — filling 4s before 3d, per the Aufbau (n …