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Chemistry · Ch 6 — Chemical Kinetics

Arrhenius equation

6.7.1

Arrhenius equation

Arrhenius suggested that the rate of a reaction varies with temperature as

k=A e−Ea/RT...6.18k = A\,e^{-E_a/RT} \qquad \text{...6.18}

where kk is the rate constant, EaE_a is the activation energy, RR the molar gas constant, TT the temperature in kelvin, and AA is the pre-exponential factor. Eq. (6.18) is called the Arrhenius equation. …