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Choose the most correct option · Q8

Q.viii. The elementary reaction O3(g)+O(g)⟶2 O2(g)\mathrm{O_3(g) + O(g) \longrightarrow 2\ O_2(g)} is a. unimolecular and second order
b. bimolecular and first order
c. bimolecular and second order
d. unimolecular and first order

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Step 1. The elementary reaction is O3(g)+O(g)→2O2(g)O_3(g)+O(g)\rightarrow 2O_2(g).

Step 2. Two reactant molecules (O3O_3 and OO) collide and react, so the molecularity is 2 (bimolecular).

Step 3. For an elementary reaction, the rate law follows directly from stoichiometry: rate=k[O3][O]\text{rate}=k[O_3][O], first order in each, giving overall order 1+1=21+1=2 (second order). …

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