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Problems · Problem 6.1

Q.For the reaction 2 N2O5(g)⟶4 NO2(g)+O2(g)\mathrm{2\ N_2O_5(g) \longrightarrow 4\ NO_2(g) + O_2(g)} in liquid bromine, N2_2O5_5 disappears at a rate of 0.02 moles dm−3^{-3} sec−1^{-1}. At what rate NO2_2 and O2_2 are formed? What would be the rate of reaction?

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N2_2O5_5 disappears at 0.02 mol dm−3^{-3} s−1^{-1}; dividing by its coefficient 2 gives rate = 0.01; O2_2 (coefficient 1) forms at 0.01 and NO2_2 (coefficient 4) at 4 ×\times 0.01 = 0.04 mol dm−3^{-3} s−1^{-1}.

Step 1. For 2 N2O5(g)⟶4 NO2(g)+O2(g)\mathrm{2\ N_2O_5(g) \longrightarrow 4\ NO_2(g) + O_2(g)}:

rate=−12d[N2O5]dt=+14d[NO2]dt=+d[O2]dt\text{rate} = -\dfrac{1}{2}\dfrac{\mathrm{d[N_2O_5]}}{\mathrm{d}t} = +\dfrac{1}{4}\dfrac{\mathrm{d[NO_2]}}{\mathrm{d}t} = +\dfrac{\mathrm{d[O_2]}}{\mathrm{d}t}

Step 2 (rate of reaction). Given −d[N2O5]/dt-\mathrm{d[N_2O_5]}/\mathrm{d}t = 0.02 mol dm−3^{-3} s−1^{-1}: rate = 12\frac{1}{2} ×\times 0.02 = 0.01 mol dm−3^{-3} s−1^{-1}. …

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