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Q.For the reaction, . Calculate the rate of formation of I, the rates of consumption of I and SO and the overall rate of reaction if the rate of formation of SO is 0.022 moles dm sec
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Start your 14-day free trial to unlock the full solution →Step 1. For 3I-(aq) + S2O8^2-(aq) -> I3-(aq) + 2SO4^2-(aq), the general rate expression is rate = -(1/3)d[I-]/dt = -(1/1)d[S2O8^2-]/dt = (1/1)d[I3-]/dt = (1/2)d[SO4^2-]/dt.
Step 2. Given d[SO4^2-]/dt = 0.022 mol dm-3 s-1, the overall rate of reaction = (1/2)(0.022) = 0.011 mol dm-3 s-1.
Step 3. Rate of formation of I3- = rate of reaction (coefficient 1) = 0.011 mol dm-3 s-1.
Step 4. Rate of consumption of S2O8^2- = rate of reaction (coefficient 1) = 0.011 mol dm-3 s-1. …
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