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Problems · Problem 4.11

Q.Estimate the standard enthalpy of combustion of CH4_4(g) if ΔfH0\Delta_f H^0(CH4_4) = -74.8 kJ mol−1^{-1}, ΔfH0\Delta_f H^0(CO2_2) = -393.5 kJ mol−1^{-1} and ΔfH0\Delta_f H^0(H2_2O) = -285.8 kJ mol−1^{-1}

Maharashtra MsbshseTextbookSubjectiveImportance★★★★★
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[(−393.5)+2(−285.8)]−[(−74.8)+0]=−890.3[(-393.5) + 2(-285.8)] - [(-74.8) + 0] = -890.3 kJ.

Step 1. The combustion reaction of methane: CH4(g)+2O2(g)→CO2(g)+2H2O(l)\mathrm{CH_4(g) + 2O_2(g) \rightarrow CO_2(g) + 2H_2O}(l), ΔrH0=?\Delta_r H^0 = ?

Step 2. ΔrH0=∑ΔfH0(products)−∑ΔfH0(reactants)\Delta_r H^0 = \sum \Delta_f H^0(\mathrm{products}) - \sum \Delta_f H^0(\mathrm{reactants}), with ΔfH0(O2)=0\Delta_f H^0(\mathrm{O_2}) = 0. …

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