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Q.Write thermochemical equation for complete oxidation of one mole of H2\mathrm{H_2}(g). Standard enthalpy change of the reaction is -286 kJ. Is the value -286 kJ, enthalpy of formation or enthalpy of combustion or both? Explain.

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Step 1. The thermochemical equation for complete oxidation of 1 mole of H2(g) is H2(g) + 1/2 O2(g) → H2O(l), ΔH0 = -286 kJ mol-1.

Step 2. By definition, an enthalpy of FORMATION is the enthalpy change forming one mole of a compound from its elements -- which is exactly what this equation shows (H2O formed from H2 and O2).

Step 3. By definition, an enthalpy of COMBUSTION is the enthalpy change when one mole of a substance is completely oxidised -- which this equation ALSO shows, since H2 is being completely burnt in O2. …

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