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Answer the following (group 2) · Q12

Q.xii. Complete the following.
  1. ICl3_3 + H2_2O ⟶\longrightarrow ........ + ...... + ICl
  2. I2_2 + KClO3_3 ⟶\longrightarrow ....... + KIO2_2
  3. BrCl + H2_2O ⟶\longrightarrow ....... + HCl
  4. Cl2_2 + ClF3_3 ⟶\longrightarrow ........
  5. H2_2C = CH2_2 + ICl ⟶\longrightarrow .......
  6. XeF4_4 + SiO2_2 ⟶\longrightarrow ....... + SiF4_4
  7. XeF6_6 + 6H2_2O ⟶\longrightarrow ........ + HF
  8. XeOF4_4 + H2_2O ⟶\longrightarrow ....... + HF
[!NOTE]
Two sub-items carry the book's own quirks, transcribed as printed: item 2 prints the product "KIO2_2" where the chapter's own special reaction (section 7.12.2) gives KIO3_3 (and only KIO3_3 balances); item 7 prints "6H2_2O ... + HF" while the chapter's own hydrolysis equation (section 7.13.2) is XeF6_6 + 3H2_2O ⟶\longrightarrow XeO3_3 + 6HF. The answer discloses both.

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Item 1. 2ICl3_3 + 3H2_2O ⟶\longrightarrow HIO3_3 + 5HCl + ICl -- section 7.12.2's own XX'3_3 hydrolysis (2 I, 6 Cl, 6 H, 3 O balance on both sides).

Item 2. I2_2 + KClO3_3, on heating, gives ICl + KIO3_3 -- the chapter's own "special reaction for ICl" (section 7.12.2). The exercise prints the second product as "KIO2_2", but only KIO3_3 balances (3 O on each side); the printed KIO2_2 is treated as a slip and disclosed, never silently used.

Item 3. BrCl + H2_2O ⟶\longrightarrow HOBr + HCl, exactly as in section 7.12.2's hydrolysis row.

Item 4. Cl2_2 + ClF3_3 ⟶\longrightarrow 3ClF -- the halogen + interhalogen comproportionation, the exact chlorine analogue of the chapter's own worked example Br2_2 + BrF3_3 ⟶\longrightarrow 3BrF (section 7.12.2, "reaction of halogen with interhalogen compounds"); 3 Cl and 3 F balance.

Item 5. H2_2C=CH2_2 + ICl ⟶\longrightarrow ICH2_2-CH2_2Cl (iodine and chlorine adding across the double bond), as illustrated in section 7.12.2's addition-across-olefins row.

Item 6. 2XeF4_4 + SiO2_2 ⟶\longrightarrow 2XeOF2_2 + SiF4_4 -- SiO2_2 converts the xenon fluoride to its oxyfluoride, the direct XeF4_4 analogue of the chapter's own 2XeOF4_4 + SiO2_2 ⟶\longrightarrow 2XeO2_2F2_2 + SiF4_4 (section 7.13.3), and XeOF2_2 is exactly the oxyfluoride the chapter's own partial hydrolysis of XeF4_4 produces (8 F, 2 Xe, 1 Si, 2 O balance). …

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