Q.xii. Complete the following.
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ICl + HO ........ + ...... + ICl
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I + KClO ....... + KIO
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BrCl + HO ....... + HCl
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Cl + ClF ........
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HC = CH + ICl .......
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XeF + SiO ....... + SiF
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XeF + 6HO ........ + HF
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XeOF + HO ....... + HF
[!NOTE]
Two sub-items carry the book's own quirks, transcribed as printed: item 2 prints the product "KIO" where the chapter's own special reaction (section 7.12.2) gives KIO (and only KIO balances); item 7 prints "6HO ... + HF" while the chapter's own hydrolysis equation (section 7.13.2) is XeF + 3HO XeO + 6HF. The answer discloses both.
Two sub-items carry the book's own quirks, transcribed as printed: item 2 prints the product "KIO" where the chapter's own special reaction (section 7.12.2) gives KIO (and only KIO balances); item 7 prints "6HO ... + HF" while the chapter's own hydrolysis equation (section 7.13.2) is XeF + 3HO XeO + 6HF. The answer discloses both.
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Start your 14-day free trial to unlock the full solution →Item 1. 2ICl + 3HO HIO + 5HCl + ICl -- section 7.12.2's own XX' hydrolysis (2 I, 6 Cl, 6 H, 3 O balance on both sides).
Item 2. I + KClO, on heating, gives ICl + KIO -- the chapter's own "special reaction for ICl" (section 7.12.2). The exercise prints the second product as "KIO", but only KIO balances (3 O on each side); the printed KIO is treated as a slip and disclosed, never silently used.
Item 3. BrCl + HO HOBr + HCl, exactly as in section 7.12.2's hydrolysis row.
Item 4. Cl + ClF 3ClF -- the halogen + interhalogen comproportionation, the exact chlorine analogue of the chapter's own worked example Br + BrF 3BrF (section 7.12.2, "reaction of halogen with interhalogen compounds"); 3 Cl and 3 F balance.
Item 5. HC=CH + ICl ICH-CHCl (iodine and chlorine adding across the double bond), as illustrated in section 7.12.2's addition-across-olefins row.
Item 6. 2XeF + SiO 2XeOF + SiF -- SiO converts the xenon fluoride to its oxyfluoride, the direct XeF analogue of the chapter's own 2XeOF + SiO 2XeOF + SiF (section 7.13.3), and XeOF is exactly the oxyfluoride the chapter's own partial hydrolysis of XeF produces (8 F, 2 Xe, 1 Si, 2 O balance). …
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