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Select appropriate answers · Q2

Q.ii. Hydrides of group 16 are weakly acidic. The correct order of acidity is A. H2_2O > H2_2S > H2_2Se > H2_2Te
B. H2_2Te > H2_2O > H2_2S > H2_2Se
C. H2_2Te > H2_2Se > H2_2S > H2_2O
D. H2_2Te > H2_2Se > H2_2O > H2_2S

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✓ Free question

Step 1. Section 7.6.2 states explicitly that the acidic character of group 16 hydrides increases from H2O to H2Te, because the H-E bond dissociation enthalpy falls steadily down the group (Table 7.5), so the bond ionises more readily in water.

Step 2. 'Increases from H2O to H2Te' means H2Te is the strongest acid and H2O is the weakest, i.e. the order from strongest to weakest is H2Te > H2Se > H2S > H2O.

Step 3. This matches option C exactly.

✓Final answer

C. H2Te > H2Se > H2S > H2O is the correct order of increasing-then-decreasing... more precisely, decreasing acidity from H2Te (strongest) down to H2O (weakest).

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