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Problems · Problem 7.5

Q.Bond dissociation enthalpy of F2_2 (158.8 KJ mol−1^{-1}) is lower than that of Cl2_2 (242.6 KJ mol−1^{-1}) Why ?
[!NOTE]
The unit is printed "KJ mol−1^{-1}" (capital K) and the stem runs straight into "Why ?" with no punctuation before it -- both the book's own style, transcribed as printed.

Maharashtra MsbshseTextbookSubjectiveImportance★★★★★
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Fluorine's small atomic size brings the two atoms' lone pairs into strong mutual repulsion, weakening the F - F bond (158.8 kJ mol−1^{-1}); in the larger Cl2_2 the lone pairs are far apart, so the Cl - Cl bond is stronger (242.6 kJ mol−1^{-1}).

Step 1. Fluorine has a smaller atomic size than chlorine, so in the F2_2 molecule the two nuclei -- and with them each atom's three lone pairs -- are held very close together.

Step 2. The lone pairs on each F atom are so close that they strongly repel each other; this repulsion works against the bonding attraction and makes the F - F bond weak, so less energy is required to break it. The textbook illustrates this inside the Problem box (its "Fig. 7.1"):

Lone pair - lone pair repulsion between the closely spaced F atoms of the F2 molecule (redrawn from the textbook's Fig. 7.1)
Lone pair - lone pair repulsion between the closely spaced F atoms of the F2 molecule (redrawn from the textbook's Fig. 7.1)
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