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Question 113 of 119

Q.Arrange the following in the increasing order of the property mentioned:

(i) HOCl, HClO2_2, HClO3_3, HClO4_4 (acidic strength)
(ii) MF, MCl, MBr, MI (ionic character)
(iii) HF, HCl, HBr, HI (thermal stability)
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2024Subjective· 3mImportance★★★★★
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Acidity: HOCl<HClO2<HClO3<HClO4. Ionic character: MI<MBr<MCl<MF. Thermal stability: HI<HBr<HCl<HF.

(i) Acidic strength of oxoacids of chlorine: acidity increases as the number of oxygen atoms (and hence the oxidation state of Cl) increases, since more OO atoms stabilise the conjugate base by delocalising the negative charge:

HOCl<HClO2<HClO3<HClO4HOCl < HClO_2 < HClO_3 < HClO_4

(ii) Ionic character of metal halides (MM = same metal): ionic character decreases as the halide ion gets larger (down the group, electronegativity of halogen decreases and covalent character increases per Fajans' rules), so it decreases F>Cl>Br>IF>Cl>Br>I; in increasing order:

MI<MBr<MCl<MFMI < MBr < MCl < MF

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