Question 113 of 119
Q.Arrange the following in the increasing order of the property mentioned:
(i) HOCl, HClO, HClO, HClO (acidic strength)
(ii) MF, MCl, MBr, MI (ionic character)
(iii) HF, HCl, HBr, HI (thermal stability)
Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2024Subjective· 3mImportance★★★★★
95% · 113/119 Questions
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Start your 14-day free trial to unlock the full solution →Acidity: HOCl<HClO2<HClO3<HClO4. Ionic character: MI<MBr<MCl<MF. Thermal stability: HI<HBr<HCl<HF.
(i) Acidic strength of oxoacids of chlorine: acidity increases as the number of oxygen atoms (and hence the oxidation state of Cl) increases, since more atoms stabilise the conjugate base by delocalising the negative charge:
(ii) Ionic character of metal halides ( = same metal): ionic character decreases as the halide ion gets larger (down the group, electronegativity of halogen decreases and covalent character increases per Fajans' rules), so it decreases ; in increasing order:
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