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Chemistry · Ch 16 — Green Chemistry and Nanochemistry

Electrical Conductivity

16.6.6

Electrical Conductivity

Electrical conductivity is another property observed to change at the nanoscale compared with bulk behaviour. The chapter's example is the carbon nanotube: depending on its exact structure (specifically, how the graphite sheet making up its wall is rolled up, though the chapter does not go into that structural detail here), a carbon nanotube can behave either as an electrical conductor or as a semiconductor. This is a genuinely unusual property for a single chemical substance (essentially pure carbon) to display -- an ordinary bulk material is either a conductor or an insulator/semiconductor, not something that can switch between the two categories depending purely on its nanoscale structural details, which is exac …