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Problems · Problem 1.4

Q.A compound is formed by two elements A and B. The atoms of element B forms ccp structure. The atoms of A occupy 1/3rd of tetrahedral voids. What is the formula of the compound?

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Tetrahedral voids = 2B; A fills 1/3 of them, so A : B = 2/3 : 1 = 2 : 3, giving A₂B₃.

Step 1. The atoms of element B form the ccp lattice. The number of tetrahedral voids generated is twice the number of atoms forming the close-packed structure: tetrahedral voids =2B= 2\text{B}. …

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