Skip to content
Question 52 of 65

Q.What is glycerose ? How is it obtained ?

Puducherry TnboardTamil Nadu HSC (DGE) Board 2019Subjective· 2mImportance★★★★★
80% · 52/65 Questions
🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

Glycerose is the collective term for the two three-carbon sugars, glyceraldehyde and dihydroxyacetone, obtained by carefully oxidising glycerol.

Glycerol, CH2OH−CHOH−CH2OHCH_2OH-CHOH-CH_2OH, has three hydroxyl groups: two primary (at C1 and C3) and one secondary (at C2). When glycerol is subjected to mild, controlled oxidation - classically with dilute nitric acid, or with bromine water/hydrogen peroxide in the presence of a ferrous salt catalyst (Fenton-type oxidation) - the alcohol groups are oxidised only as far as the aldehyde/ketone stage (over-oxidation would carry them further to carboxylic acids, which is avoided by controlling the conditions).

Oxidation of a primary −CH2OH-CH_2OH group gives an aldehyde group (−CHO-CHO), producing glyceraldehyde:

CH2OH−CHOH−CH2OH→[O]CH2OH−CHOH−CHOCH_2OH-CHOH-CH_2OH \xrightarrow{[O]} CH_2OH-CHOH-CHO

Oxidation of the secondary −CHOH−-CHOH- group gives a ketone group, producing dihydroxyacetone:

CH2OH−CHOH−CH2OH→[O]CH2OH−CO−CH2OHCH_2OH-CHOH-CH_2OH \xrightarrow{[O]} CH_2OH-CO-CH_2OH

…

Unlock everything free for 14 days

  • Full step-by-step solutions
  • Concept-first explanations
  • Methods, shortcuts & mistakes
  • PYQ mapping + timed mock tests

Full access for 14 days. No credit card required.