Q.What is glycerose ? How is it obtained ?
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Start your 14-day free trial to unlock the full solution →Glycerose is the collective term for the two three-carbon sugars, glyceraldehyde and dihydroxyacetone, obtained by carefully oxidising glycerol.
Glycerol, , has three hydroxyl groups: two primary (at C1 and C3) and one secondary (at C2). When glycerol is subjected to mild, controlled oxidation - classically with dilute nitric acid, or with bromine water/hydrogen peroxide in the presence of a ferrous salt catalyst (Fenton-type oxidation) - the alcohol groups are oxidised only as far as the aldehyde/ketone stage (over-oxidation would carry them further to carboxylic acids, which is avoided by controlling the conditions).
Oxidation of a primary group gives an aldehyde group (), producing glyceraldehyde:
Oxidation of the secondary group gives a ketone group, producing dihydroxyacetone:
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