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Question 50 of 65

Q.Sucrose contains glucose and fructose linked by :

(a) C1−C6C_1-C_6
(b) C1−C4C_1-C_4
(c) C1−C2C_1-C_2
(d) C1−C1C_1-C_1
Puducherry TnboardTamil Nadu HSC (DGE) Board 2019MCQ· 1mImportance★★★★★
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The glycosidic bond in sucrose links glucose's C1C_1 (anomeric carbon) directly to fructose's C2C_2 (its anomeric carbon), which is why sucrose has no free reducing group.

Glucose exists in its pyranose ring form with the anomeric carbon at C1C_1, and fructose exists in its furanose ring form with the anomeric carbon at C2C_2. In sucrose, these two anomeric carbons are joined directly to each other through a shared oxygen — an α(1→2)β\alpha(1\rightarrow2)\beta glycosidic linkage — rather than one anomeric carbon linking to a non-anomeric −OH-OH of the other sugar. Because both anomeric carbons are tied up in this linkage, neither sugar unit can open to expose a free aldehyde/ketone g …

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