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Question 75 of 80

Q.Write Arrhenius equation and explain the terms involved.

Puducherry TnboardTamil Nadu HSC (DGE) Board 2024Subjective· 3mImportance★★★★★
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The Arrhenius equation, k=Ae−Ea/RTk=Ae^{-E_a/RT}, is the fundamental relationship showing how a reaction's rate constant depends exponentially on temperature and activation energy, with AA capturing the frequency and orientation of effective molecular collisions.

The Arrhenius equation is written: k=A e−Ea/RTk = A\,e^{-E_a/RT} where:

  • kk is the rate constant of the reaction at temperature TT.
  • AA is the pre-exponential factor (also called the frequency factor or Arrhenius factor) — related to the frequency of collisions between reactant molecules and the fraction of those collisions having the correct orientation for reaction; it has the same units as kk.
  • EaE_a is the activation energy of the reaction — the minimum extra energy that colliding reactant molecules must possess (over their average energy) for the reaction to occur, usually expressed in J mol−1J\,mol^{-1} or kJ mol−1kJ\,mol^{-1}.
  • RR is the universal gas constant (8.314 J K−1mol−18.314\ J\,K^{-1}mol^{-1}).
  • TT is the absolute temperature (in Kelvin). …

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