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Question 76 of 80

Q.During the decomposition of H2O2H_2O_2 to give dioxygen, 48 g O2O_2 is formed per minute at certain point of time. The rate of formation of water at this point is :

(a) 2.25 mol min−12.25\ mol\ min^{-1}
(b) 0.75 mol min−10.75\ mol\ min^{-1}
(c) 3.0 mol min−13.0\ mol\ min^{-1}
(d) 1.5 mol min−11.5\ mol\ min^{-1}
Puducherry TnboardTamil Nadu HSC (DGE) Board 2025MCQ· 1mImportance★★★★★
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Using the balanced equation 2H2O2→2H2O+O22H_2O_2\rightarrow 2H_2O+O_2, the rate of O2O_2 formation is found from the given mass, and the rate of water formation is twice that (since H2OH_2O and H2O2H_2O_2 share the coefficient 2, while O2O_2 has coefficient 1).

For the reaction 2H2O2(aq)→2H2O(l)+O2(g)2H_2O_2(aq) \rightarrow 2H_2O(l) + O_2(g), the rate of reaction is expressed uniformly across all species using their stoichiometric coefficients: Rate=−12d[H2O2]dt=12d[H2O]dt=d[O2]dt\text{Rate} = -\dfrac{1}{2}\dfrac{d[H_2O_2]}{dt} = \dfrac{1}{2}\dfrac{d[H_2O]}{dt} = \dfrac{d[O_2]}{dt}

Step 1 — rate of O2O_2 formation: 48 g48\ g of O2O_2 forms per minute. Molar mass of O2=32 g mol−1O_2 = 32\ g\,mol^{-1}, so d[O2]dt=4832=1.5 mol min−1\dfrac{d[O_2]}{dt} = \dfrac{48}{32} = 1.5\ mol\,min^{-1}

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