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Question 74 of 80

Q.What is an order of a reaction ?

Puducherry TnboardTamil Nadu HSC (DGE) Board 2024Subjective· 2mImportance★★★★★
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For a rate law rate=k[A]x[B]y…rate=k[A]^x[B]^y\ldots, obtained purely from experimental data, the order of the reaction is defined as the sum x+y+…x+y+\ldots of the individual concentration exponents.

For a general reaction with rate law rate=k[A]x[B]yrate=k[A]^x[B]^y (where xx and yy are experimentally determined exponents, called the order of the reaction with respect to A and B respectively), the overall order of the reaction is the algebraic sum of these individual orders: order=x+y\text{order}=x+y. Crucially, the order of a reaction is an experimentally measured quantity — determined by studying how the rate actually changes with concentration — and it may or may not be equal to the stoichiometric coefficients of the reactants in the balanced chemical equation (this only coincides for elementary/single-step reactions). The order can be zero, a positive integer, a negative number, or even a fraction, and is a purely empirical description of how the rate depends on concentration, dis …

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