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Write Brief Answer · Q19

Q.Solubility product of Ag2CrO4Ag_2CrO_4 is 1×10−121 \times 10^{-12}. What is the solubility of Ag2CrO4Ag_2CrO_4 in 0.01M AgNO3AgNO_3 solution?

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Step 1. Ag2CrO4(s)⇌2Ag+(aq)+CrO42−(aq)Ag_2CrO_4(s) \rightleftharpoons 2Ag^+(aq)+CrO_4^{2-}(aq). Let ss = molar solubility of Ag2CrO4Ag_2CrO_4 in the 0.01M AgNO3AgNO_3 solution.

Step 2. Since AgNO3AgNO_3 supplies 0.01M Ag+Ag^+ directly, and Ag2CrO4Ag_2CrO_4's own contribution (2s2s) is expected to be negligible by comparison (common-ion suppression), [Ag+]≈0.01[Ag^+]\approx0.01 M. [CrO42−]=s[CrO_4^{2-}]=s (entirely from Ag2CrO4Ag_2CrO_4). …

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