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Q.KspK_{sp} of AgCl is 1.8×10−101.8 \times 10^{-10}. Calculate its molar solubility in 1M AgNO3AgNO_3.

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Step 1. AgCl(s)⇌Ag+(aq)+Cl−(aq)AgCl(s) \rightleftharpoons Ag^+(aq)+Cl^-(aq), Ksp=1.8×10−10K_{sp}=1.8\times10^{-10}.

Step 2. In 1M AgNO3AgNO_3, [Ag+]≈1[Ag^+]\approx1 M (the tiny extra Ag+Ag^+ from AgCl's own dissolution, equal to ss, is utterly negligible next to 1 M). …

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