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Q.How will you convert boric acid to boron nitride ?

Puducherry TnboardTamil Nadu HSC (DGE) Board 2024Subjective· 2mImportance★★★★★
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Heating boric acid drives off water to give boric anhydride (B2O3B_2O_3), which is then heated with ammonia at high temperature to form boron nitride, an inorganic analogue of graphite/diamond.

Step 1 — Dehydration of boric acid: On heating, boric acid loses water in stages, ultimately forming boron trioxide (boric anhydride): 2H3BO3→ΔB2O3+3H2O2H_3BO_3 \xrightarrow{\Delta} B_2O_3 + 3H_2O

Step 2 — Formation of boron nitride: Boron oxide is then heated strongly with excess ammonia gas at a high temperature (around 1073-1273 K), where ammonia both nitrides and reduces/displaces the oxide: B2O3+2NH3→Δ2BN+3H2OB_2O_3 + 2NH_3 \xrightarrow{\Delta} 2BN + 3H_2O Boron nitride (BN) is a white, slippery solid; its 'white graphite' hexagonal form (isoelectronic and isostructural with graphite) consists of alternating B and N atoms in a hexagonal layered lattice, giving i …

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