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Question 46 of 47

Q.Boric acid is an acid because its molecule :

(a) combines with proton to form water molecule.
(b) contains replaceable H+H^+ ion.
(c) accepts OH−OH^- from water, releasing proton.
(d) gives up a proton.
Puducherry TnboardTamil Nadu HSC (DGE) Board 2025MCQ· 1mImportance★★★★★
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Boric acid, B(OH)3B(OH)_3, does not itself ionise to release an H+H^+; it acts as a Lewis acid because the electron-deficient boron accepts a hydroxide ion donated by a water molecule, and it is that water molecule which then releases the proton — making boric acid monobasic and weak.

Boron in B(OH)3B(OH)_3 has only 6 electrons around it (an incomplete octet), making it electron-deficient and a good Lewis acid (electron-pair acceptor). It does not contain any ionisable O−HO-H proton that behaves as a classical Bronsted acid on its own. Instead, it reacts with water as follows: B(OH)3+2H2O⇌[B(OH)4]−+H3O+B(OH)_3 + 2H_2O \rightleftharpoons [B(OH)_4]^- + H_3O^+ Here, the boron atom accepts a hydroxide ion, OH−OH^-, from a water molecule (completing its octet, forming the tetrahedral borate anion [B(OH)4]−[B(OH)_4]^-), and that water molecule, having donated its OH−OH^-, is left a …

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