Skip to content
Question 66 of 71

Q.What are the factors affecting the Mean Free Path?

Tamil Nadu DgeTamil Nadu HSC First Year (DGE) Board 2025Subjective· 2mImportance★★★★★
93% · 66/71 Questions
🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

Mean free path lambda = 1/(sqrt(2) pi d^2 n) depends directly on the molecular diameter d and the number density n of the gas, and indirectly on pressure and temperature through n.

The mean free path is the average distance a gas molecule travels between two successive collisions with other molecules. The kinetic theory expression is:

lambda = 1 / (sqrt(2) pi d^2 n)

where d is the diameter of a molecule and n is the number of molecules per unit volume (number density).

Factors affecting it:

  1. Number density (n): A denser gas (more molecules packed into the same volume) means a molecule encounters other molecules more often, so lambda is smaller. lambda is inversely proportional to n.
  2. Molecular diameter (d): Larger molecules present a bigger effective 'target' cross-sectional area (proportional to d^2) for collisions, so bigger molecules mean more frequent collisions and a smaller lambda. lambda is inversely proportional to d^2. …

Unlock everything free for 14 days

  • Full step-by-step solutions
  • Concept-first explanations
  • Methods, shortcuts & mistakes
  • PYQ mapping + timed mock tests

Full access for 14 days. No credit card required.