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Chemistry · Ch 1 — Some Basic Concepts of Chemistry

Law of Definite Proportions

1.5.2

Law of Definite Proportions

This law — which the book notes is sometimes also referred to as the Law of Definite Composition (equivalently, of constant composition) — states that a given chemical compound always contains its constituent elements in a fixed ratio by mass, regardless of its source or method of preparation. For instance, pure water (H2OH_2O) from any source—rain, river, or laboratory synthesis—will always consist of hydrogen and oxygen in a mass ratio of 1:81:8. This fundamental principle arises from the fact that atoms of each element have a fixed, characteristic mass, and they combine in definite whole-number ratios to form molecules.

Proust's own supporting evidence for this law came from cupric carbonate (copper carbonate). He analysed two samples -- one occurring naturally, the other prepared synthetically in the laboratory -- and found the percentage of copper, carbon, and oxygen was identical in both, regardless of the very different origins of the two samples. …

Table unnumbered-table-1.5.2-copper-carbonatePercentage composition of copper, carbon, and oxygen in natural and synthetic samples of cupric carbonate, illustrating the law of definite proportions (Proust's data).
% of copper% of carbon% of oxygen
Natural Sample51.359.7438.91