Chemistry · Ch 1 — Some Basic Concepts of Chemistry
Law of Definite Proportions
Law of Definite Proportions
This law — which the book notes is sometimes also referred to as the Law of Definite Composition (equivalently, of constant composition) — states that a given chemical compound always contains its constituent elements in a fixed ratio by mass, regardless of its source or method of preparation. For instance, pure water () from any source—rain, river, or laboratory synthesis—will always consist of hydrogen and oxygen in a mass ratio of . This fundamental principle arises from the fact that atoms of each element have a fixed, characteristic mass, and they combine in definite whole-number ratios to form molecules.
Proust's own supporting evidence for this law came from cupric carbonate (copper carbonate). He analysed two samples -- one occurring naturally, the other prepared synthetically in the laboratory -- and found the percentage of copper, carbon, and oxygen was identical in both, regardless of the very different origins of the two samples. …
| % of copper | % of carbon | % of oxygen | |
|---|---|---|---|
| Natural Sample | 51.35 | 9.74 | 38.91 |