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Exercise · Q29

Q.Classify the following reaction as addition, elimination or substitution: CH3-CH2-OH + HBr -> CH3-CH2-Br + H2O.

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In CH3−CH2−OH+HBr→CH3−CH2−Br+H2O\text{CH}_3-\text{CH}_2-\text{OH} + \text{HBr} \rightarrow \text{CH}_3-\text{CH}_2-\text{Br} + \text{H}_2\text{O}, the hydroxyl group of ethanol is replaced by a bromine atom, while the rest of the carbon skeleton (CH3−CH2−\text{CH}_3-\text{CH}_2-) and its degree of saturation stay completely unchanged -- no multiple bond is created or destroyed, and one group (−OH-\text{OH}) is simply swapped for another (−Br-\text{Br}). This atom-for-atom replacement, with the rest of the molecule left intact, is the defining feature of a substitution reaction. …

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