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Exercise · Q9

Q.State Newton's law of viscosity, writing it as an equation, and explain the physical meaning and SI unit of the coefficient of viscosity of a fluid. How does the viscosity of a liquid generally change as its temperature is raised, and how does this differ from the way the viscosity of a gas changes with temperature?

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Newton's law of viscosity states that the tangential (viscous) force FF needed to maintain a steady relative velocity between two adjacent layers of a fluid is directly proportional to the area of contact AA between the layers and to the velocity gradient dv/dxdv/dx set up between them:

F=ηAdvdxF = \eta A \frac{dv}{dx}

The constant of proportionality, η\eta, is the coefficient of viscosity. Physically, η=F/Adv/dx\eta = \dfrac{F/A}{dv/dx} is the tangential force per unit area required to maintain a unit velocity gradient in the fluid -- a fluid with a large η\eta (such as glycerine or honey) needs a much larger force to shear it at a given rate than a fluid with a small η\eta (such as water or air). Since F/AF/A is in Pa\text{Pa} and dv/dxdv/dx is in s−1\text{s}^{-1}, η\eta has SI unit Pa⋅s\text{Pa·s} (also called the poiseuille).

Effect of temperature: for a liquid, viscosity arises mainly from intermolecular cohesive forces between neighbouring molecules; raising the temperature gives the molecules more thermal energy, weakening the effectiveness of these cohesive forces, so the liquid's viscosity decreases. For a gas, viscosity arises mainly from the transfer of momentum as molecules dart between adjacent layers; raising the temperature increases the average molecular speed, increasing this rate of momentum transfer, so the gas's viscosity increases -- the opposite trend to a liquid.

✓Final answer

F=ηA(dv/dx)F = \eta A(dv/dx); η\eta's SI unit is Pa⋅s\text{Pa·s}. Liquids get less viscous as temperature rises; gases get more viscous as temperature rises.

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