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Numerical · Q20

Q.10001000 identical small spherical water droplets, each of radius 1.0×10−4 m1.0\times10^{-4}\ \text{m}, coalesce (join together) to form a single large spherical drop, with no change in the total volume of water. Taking the surface tension of water as 0.072 N/m0.072\ \text{N/m}, calculate

(a) the radius of the resulting large drop, and
(b) the energy released as surface energy in the process of coalescence.
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Given: n=1000n = 1000, r=1.0×10−4 mr = 1.0\times10^{-4}\ \text{m}, T=0.072 N/mT = 0.072\ \text{N/m}.

  1. Radius of the large drop, from conservation of volume, n×43πr3=43πR3n\times\tfrac43\pi r^3 = \tfrac43\pi R^3, so R=n1/3rR = n^{1/3}r:

    R=(1000)1/3×(1.0×10−4)=10×1.0×10−4=1.0×10−3 mR = (1000)^{1/3}\times(1.0\times10^{-4}) = 10\times1.0\times10^{-4} = 1.0\times10^{-3}\ \text{m}

  2. Energy released. Total surface area before coalescence:

    Abefore=n×4πr2=1000×4π×(1.0×10−4)2=1.2566×10−4 m2A_{\text{before}} = n\times4\pi r^2 = 1000\times4\pi\times(1.0\times10^{-4})^2 = 1.2566\times10^{-4}\ \text{m}^2

    Surface area of the single large drop after coalescence:

    Aafter=4πR2=4π×(1.0×10−3)2=1.2566×10−5 m2A_{\text{after}} = 4\pi R^2 = 4\pi\times(1.0\times10^{-3})^2 = 1.2566\times10^{-5}\ \text{m}^2

    Decrease in total surface area: ΔA=Abefore−Aafter=1.2566×10−4−1.2566×10−5=1.1310×10−4 m2\Delta A = A_{\text{before}} - A_{\text{after}} = 1.2566\times10^{-4} - 1.2566\times10^{-5} = 1.1310\times10^{-4}\ \text{m}^2 …

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