Q.In the Bohr model of the hydrogen atom, an electron revolves in the first orbit of radius 5.29×10−11 m with a speed of 2.19×106 m/s. Calculate the orbital magnetic moment of the electron in this orbit, and compare it with the value of the Bohr magneton, 9.27×10−24 A⋅m2.
Concept understanding — Bohr Magneton
The first time you meet the Bohr magneton, it can feel like a random number with a weird unit. But it is actually one of the most natural constants in atomic physics — it is the smallest possible magnetic moment that an electron can have, simply by moving around.
The intuition: a tiny current loop
Imagine an electron whizzing around a nucleus in a circular orbit. A moving charge is an electric current. A loop of current is a tiny magnet — it has a magnetic moment. The magnetic moment tells you how strong that little magnet is and how it will twist in an external magnetic field.
For a single electron in a circular orbit, the magnetic moment turns out to be proportional to the orbital angular momentum. The constant of proportionality is the Bohr magneton. In other words, if you know how much angular momentum the electron has, you multiply by μB to get its magnetic moment.
The same idea applies to the electron's spin. Even though spin is not a literal spinning motion, it also produces a magnetic moment, and the natural unit for that is again μB (though the exact factor is slightly different — the spin g-factor is about 2).
So the Bohr magneton is the fundamental quantum of magnetic moment for an electron. Any atomic magnetic moment is an integer multiple (or a simple fraction) of μB.
The precise statement
The Bohr magneton is defined as:
μB=2meeℏ
where:
- e is the elementary charge (1.602×10−19 C)
- ℏ is the reduced Planck constant (h/2π=1.055×10−34 J·s)
- me is the electron mass (9.109×10−31 kg)
Plugging these numbers gives:
μB=9.274×10−24 J/T
The unit J/T (joule per tesla) is the unit of magnetic moment. It tells you the energy of interaction when the magnet is placed in a magnetic field: E=−μ⋅B.
Why this combination?
The formula eℏ/2me is not pulled from thin air. It comes directly from classical physics applied to a quantum orbit. For an electron in a circular orbit of radius r with speed v:
- Orbital angular momentum: L=mevr
- Current: I=Te=2πrev (charge per period)
- Magnetic moment of a current loop: μ=I×area=2πrev⋅πr2=2evr
Now compare μ and L:
μ=2evr=2mee(mevr)=2meeL
So the magnetic moment is 2mee times the angular momentum. In quantum mechanics, angular momentum comes in units of ℏ. So the smallest non-zero magnetic moment from orbital motion is when L=ℏ, giving μ=eℏ/2me.
| Quantity | Symbol | Value |
|----------|--------|-------|
| Bohr magneton | μB | 9.274×10−24 J/T |
| In eV/T | μB | 5.788×10−5 eV/T |
| In cm−1/T | μB/hc | 0.467 cm−1/T |
What it means in practice
When you study the Zeeman effect (splitting of spectral lines in a magnetic field), the energy shift of an atomic level is typically μBB times some small integer. When you calculate the magnetic moment of an atom, you always get an answer that is a multiple of μB. It is the natural yardstick.
The Bohr magneton is to magnetic moments what the elementary charge e is to electric charges — the fundamental quantum.
The Bohr magneton is a constant-based CBSE Class 12 Physics NCERT topic, commonly searched as Bohr magneton value and formula class 12 or Bohr magneton derivation important questions. As the natural unit of atomic magnetic moment, it links Magnetism and Matter to the atomic-physics topics also tested in JEE Main and NEET physics.
I=ev/2πr, then μl=I×πr2; comes out equal to the Bohr magneton.
μl≈9.27×10−24 A⋅m2, equal to one Bohr magneton.
Given r=5.29×10−11 m, v=2.19×106 m/s, e=1.6×10−19 C.
Equivalent current:
I=2πrev=2π(5.29×10−11)(1.6×10−19)(2.19×106)
Numerator: 1.6×10−19×2.19×106=3.504×10−13.
Denominator: 2π×5.29×10−11=3.324×10−10.
I=3.324×10−103.504×10−13≈1.054×10−3 A
Orbital magnetic moment:
μl=I×πr2=(1.054×10−3)×π×(5.29×10−11)2
πr2=π×2.798×10−21≈8.79×10−21 m2.
μl≈(1.054×10−3)×(8.79×10−21)≈9.27×10−24 A⋅m2
This matches the Bohr magneton exactly, as it must -- the first Bohr orbit is precisely the orbit for which the quantised orbital moment equals μB (Section 1.3).
μl≈9.27×10−24 A⋅m2 -- exactly one Bohr magneton, confirming the quantisation result of Section 1.3.
Compute the equivalent orbital current I=ev/2πr first, then multiply by the orbit's area πr2 to get μl.
- Using the diameter instead of the radius in πr2.
- Forgetting to square r when computing the area.
- CBSE 2019Set 55/2/13 marksQ.Prove that the magnetic moment of the electron revolving around a nucleus in an orbit of radius r with orbital speed v is equal to evr/2. Hence using Bohr's postulate of quantization of angular momentum, deduce the expression for the magnetic moment of hydrogen atom in the ground state.
›Reveal solutionSolution
The magnetic moment of an orbiting electron is derived from its equivalent current loop, giving μ=evr/2. Using Bohr's quantization mvr=ℏ, the ground-state magnetic moment of hydrogen becomes μ=eℏ/2m, which is one Bohr magneton.
The key insight is that a moving charge creates a current, and a current loop has a magnetic moment. For an electron orbiting a nucleus, we can treat its circular path as a tiny current loop. The magnetic moment depends on the current (charge per unit time passing a point) and the area of the loop. Once we have the classical expression, Bohr's quantum condition fixes the angular momentum, which then determines the magnetic moment for the ground state.
Let's work through this step by step.
- Current due to the orbiting electron The electron of charge e (magnitude) completes one revolution in time T=2πr/v. The current I is the charge passing a point per unit time:
I=Te=2πr/ve=2πrev.
This is the effective current in the loop.
- Magnetic moment of a current loop For a planar loop of area A, the magnetic moment μ is I×A, directed perpendicular to the plane (right-hand rule). Here the area is πr2, so
μ=I⋅A=(2πrev)⋅(πr2)=2evr.
That's the first result: μ=evr/2.
TipNotice the factor 1/2 comes from the geometry — the current expression already has a 1/(2πr), which cancels one factor of r from the area, leaving r/2. This is a clean, cancellation-heavy derivation.
- Relating to angular momentum The orbital angular momentum of the electron (magnitude) is L=mvr, where m is the electron mass. So we can write
μ=2me(mvr)=2meL.
This shows that the magnetic moment is proportional to the angular momentum, with the constant e/(2m) called the gyromagnetic ratio.
- Applying Bohr's quantization Bohr's postulate says that angular momentum in a stationary orbit is an integer multiple of ℏ=h/(2π):
L=nℏ,n=1,2,3,…
For the ground state of hydrogen, n=1, so L=ℏ.
- Ground-state magnetic moment Substituting L=ℏ into μ=(e/2m)L gives
μ=2me⋅ℏ=2meℏ.
This quantity is known as the Bohr magneton, denoted μB. It is the fundamental unit of magnetic moment for atomic-scale currents.
Watch outA common mistake is to forget that the electron's charge is negative. The magnitude of the magnetic moment is evr/2, but the direction is opposite to the angular momentum vector because the electron has negative charge. In vector form: μ=−2meL. For the ground state, the magnitude is μB, but the vector points opposite to L.
μground state=2meℏ=μB≈9.27×10−24J/T
✓Final answerThe magnetic moment of the electron in the ground state of hydrogen is 2meℏ, which is one Bohr magneton.
🎓Unlock everything free for 14 days
- ✓Full step-by-step solutions
- ✓Concept-first explanations
- ✓Methods, shortcuts & mistakes
- ✓PYQ mapping + timed mock tests
Full access for 14 days. No credit card required.