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NCERT Exemplar · Q22

Q.A cubic unit cell of cesium chloride (CsCl) has cesium atoms situated at the eight corners of a cube of side 0.40 nm0.40\text{ nm}, and a chlorine atom situated at the centre of the cube. Each Cs atom is deficient by one electron, so it carries a charge +e+e; the Cl atom carries one excess electron, so it carries a charge −e-e.

(i) What is the net electric field at the Cl atom (the cube centre) due to the eight Cs atoms?
(ii) Suppose the Cs atom at one corner A is removed. What is the net force on the Cl atom due to the seven remaining Cs atoms?
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Because the eight Cs+^+ charges sit at corners that pair up diametrically across the centre, their fields at the Cl atom cancel and the net field is zero. When one Cs+^+ is removed, the remaining seven give a net force equal in magnitude and opposite in direction to the force the removed charge alone would have exerted — about 1.92×10−9 1.92\times10^{-9}\,N, pointing away from the missing corner.

(i) Net field at Cl

The eight corners occur in four pairs, each pair lying on a body diagonal on opposite sides of the centre and equidistant from it. The two Cs+^+ of a pair produce equal and opposite fields at the centre, which cancel. Summing over the four pairs:

E⃗net=0.\vec{E}_{net} = 0.

(ii) Net force after removing the corner charge at A

Use superposition. With all eight present the force on Cl is zero:

F⃗8=F⃗A+F⃗other 7=0  ⇒  F⃗other 7=−F⃗A.\vec{F}_{8} = \vec{F}_A + \vec{F}_{other\ 7} = 0 \;\Rightarrow\; \vec{F}_{other\ 7} = -\vec{F}_A.

So the seven remaining charges give a force equal and opposite to the force F⃗A\vec{F}_A that the removed Cs+^+ at A exerted on Cl. Since Cs+^+ attracted the Cl−^- toward A, −F⃗A-\vec{F}_A points away from A (along the body diagonal, toward the diagonally opposite corner). Equivalently, removing a +e+e is like adding a −e-e at A, which repels the Cl−^-.

Magnitude. The corner-to-centre distance is half the body diagonal: …

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